The two keys PrintScrn/SysRq and Pause/Break are special in that they have two keycodes: the former has keycode 84 when Alt is pressed simultaneously, and keycode 99 otherwise; the latter has keycode 101 when Ctrl is pressed simultaneously, and keycode 119 otherwise. (Thus, it makes no sense to bind functions to Alt keycode 99 or Ctrl keycode 119.)
If you have strange keys, that do not generate any code under Linux (or generate messages like "unrecognized scancode"), and your kernel is 1.1.63 or later, then you can use setkeycodes(1) to tell the kernel about them. They won't work under X, however. Once they have gotten a keycode from setkeycodes, they can be assigned a function by loadkeys.